High-temperature oxidation resistance of composite materials and coatings on the titanium-chromium diboride base

1Konoval, VP
1I. M. Frantsevich Institute for Problems of Materials Sciences of the NAS of Ukraine, Kyiv
Dopov. Nac. akad. nauk Ukr. 2015, 5:83-89
Section: Materials Science
Language: Russian

The high-temperature oxidation behavior of titanium-chromium diboride and composites and coatings on its base has been investigated at 800 and 1000 ºC in air. The obtained kinetic curves of isothermal oxidation follow the parabolic shape, which testifies to the formation of protective oxide films on the specimen surface. Pure TiCrB2 has higher heat resistance as compared with those of TiCrB2−NiAlCr composite and detonation coatings on it. The oxidation rate constants and the energy of activation in the 800–1000 ºC temperature range have been calculated. The films consisting of TiO2 and B2O3 are formed on the surface of oxidized TiCrB2 specimens. On the TiCrB2−NiAlCr composite surface, a small amount of Al2O3 has been additionally formed.

Keywords: composite materials, detonation coating, high temperature oxidation, titanium–chromium diboride
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