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Influence of the composition on the organization of a layered perovskite-like structure of indates AIILaInO4

TitleInfluence of the composition on the organization of a layered perovskite-like structure of indates AIILaInO4
Publication TypeJournal Article
Year of Publication2017
AuthorsTitov, Yu.A, Belyavina, NM, Slobodyanik, MS, Babaryk, AA, Timoschenko, MV
Abbreviated Key TitleDopov. Nac. akad. nauk Ukr.
DOI10.15407/dopovidi2017.04.070
Issue4
SectionChemistry
Pagination70-75
Date Published4/2017
LanguageUkrainian
Abstract

The phase Sr0.7Ca0.3LaInO4 has been synthesized by heat treatment of co-crystallized nitrates, and its layered perovskite-like structures (LPS) has been determined by X-ray powder diffraction. It is found that Sr0.7Ca0.3LaInO4 is isostructural to SrLaInO4 (sp. gr. Pbca). Influence of the composition on the organization of LPS mono-layered indates AIILnInO4 is established. It has been shown that the substitution of atoms in the A-position by smaller ones in the AIILnInO4 LPS results in an increase of the deformation degree of the (AII, Ln)O9 polyhedra, which destabilizes their LPS.

Keywordsindates AIILnInO4, layered perovskite-like structure, X-ray powder diffraction
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