Study of the structure and properties of the lanthanides tetrakis-compounds with N-(bis-(benzylamino)phosphoryl)-tosylamide

TitleStudy of the structure and properties of the lanthanides tetrakis-compounds with N-(bis-(benzylamino)phosphoryl)-tosylamide
Publication TypeJournal Article
Year of Publication2015
AuthorsPrytula, AYu., Trush, VA, Sliva, TYu., Litsis, OO, Nedilko, SG, Amirkhanov, VM
Abbreviated Key TitleDopov. Nac. akad. nauk Ukr.
DOI10.15407/dopovidi2015.02.117
Issue2
SectionChemistry
Pagination117-122
Date Published2/2015
LanguageUkrainian
Abstract
The new ligand N-(bis(benzylamino)phosphoryl)-tosylamide $\rm (HL)$ and the neutral salt $\rm NaL$ on its base have been synthesized. Coordination compounds of lanthanides are separated in the individual state by the general formula $\rm Na[LnL_{4}]$. They have been studied by the methods of IR, NMR, and electronic spectroscopy. Based on these data, the coordination mode of ligands and the composition of coordination compounds have been suggested. The efficient europium photoluminescence has been confirmed in the $\rm Na[EuL_{4}]$ solid state complex.
Keywordscoordination compounds, europium, ligand, photoluminescence
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