Classical, barrierless, and activationless discharge of palladium(II) iminodiacetate complexes

TitleClassical, barrierless, and activationless discharge of palladium(II) iminodiacetate complexes
Publication TypeJournal Article
Year of Publication2016
AuthorsKublanovsky, VS, Nikitenko, VN
Abbreviated Key TitleDopov. Nac. akad. nauk Ukr.
DOI10.15407/dopovidi2016.10.067
Issue10
SectionChemistry
Pagination67-72
Date Published10/2016
LanguageRussian
Abstract

The kinetic (exchange currents, apparent electron transfer coefficients) and energy (activation energy of diffusion and electron-transfer reaction) parameters of barrierless, ordinary (classic), and activationless discharge bis-iminodiacetate complexes of palladium(II) are determined. The actual and true activation energies and the latent heat of the electrode process are calculated.

Keywordsactivationless discharge, actual activation energy, barrierless discharge, classical discharge, latent heat of the electrode process, palladium(II) iminodiacetate complexes, true activation energy
References: 
  1. Kravtsov V.I. Rus. J. Elektrochem., 2004, 40, No 12: 1494-1502 (in Russian).
  2. Kyblanovsky V.S., Nikitenko V.N. Electrochim. Acta, 2011, 56: 2110-2115. https://doi.org/10.1016/j.electacta.2010.11.028
  3. Kyblanovsky V.S., Nikitenko V.N., Rudenko K.P. Ukr. Khim. Zhurn., 2012, 78, No 5: 47-51 (in Russian).
  4. Kyblanovsky V.S., Nikitenko V.N. J. Electroanal. Chem., 2013, 699: 14-20. https://doi.org/10.1016/j.jelechem.2013.03.021
  5. Damaskin B.B., Petrii O.A., Tsyrlina G.A. Elektrochemistry, Moscow: Khimiya, 2006 (in Russian).
  6. Kublanovsky V.S., Nikitenko V.N., Rudenko K.P. Amer. J. Anal. Chem., 2013, 4: 642-646. https://doi.org/10.4236/ajac.2013.411076
  7. Kublanovsky V.S., Nikitenko V.N., Rudenko K.P. Ukr. Khim. Zhurn., 2009, 75, No 7: 56-61.
  8. Bard A.J., Faulkner L.R. Electrochemical Methods. Fundamental and Applications, New York: Wiley, 2001.
  9. Gorodyskii A.V. Voltammetry. Kinetic of Stationary Electrolysis, Kiev: Nauk. Dumka, 1988 (in Russian).