Title | The coaction of metallic Co and Mn microparticles and N-hydroxyphthalimide in the liquid-phase oxidation of cumene |
Publication Type | Journal Article |
Year of Publication | 2017 |
Authors | Opeida, IA, Gladyshevskii, RE, Grynda, YM, Starchevskyy, VL, Kusch, OV, Kompanets, MO, Hrynchuk, YM |
Abbreviated Key Title | Dopov. Nac. akad. nauk Ukr. |
DOI | 10.15407/dopovidi2017.08.080 |
Issue | 8 |
Section | Chemistry |
Pagination | 80-85 |
Date Published | 8/2017 |
Language | Ukrainian |
Abstract | The action of metallic microparticles Co and Mn (CoMP and MnMP) in the process of radical-chain oxidation of cumene initiated with azobisisobutyronitrile by molecular oxygen in a solution of acetonitrile is investigated. A growth of the reaction rate in the case of adding the catalyst mixture of N-hydroxyphthalimide and MeMP is found. It is shown that the catalytic effect of CoMP and MnMP may be explained by their participation in the initiation stage of oxidation. |
Keywords | Co and Mn microparticles, molecular oxygen, N-hydroxyphthalimide, radical chain oxidation catalysis |
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